Now here’s some fun stuff to chew if you’re into the evolution of life on Earth.
http://www.sciencedaily.com/releases/2014/04/140425075235.htm A reconstruction of Earth's earliest ocean in the laboratory revealed the spontaneous occurrence of the chemical reactions used by modern cells to synthesize many of the crucial organic molecules of metabolism. Previously, it was assumed that these reactions were carried out in modern cells by metabolic enzymes, highly complex molecular machines that came into existence during the evolution of modern organisms. {…} The observed chemical reactions occurred in the absence of enzymes but were made possible by the chemical molecules found in the Archean sea. Finding a series of reactions that resembles the "core of cellular metabolism" suggests that metabolism predates the origin of life. This implies that, at least initially, metabolism may not have been shaped by evolution but by molecules like RNA formed through the chemical conditions that prevailed in the earliest oceans. "Our results demonstrate that the conditions and molecules found in the Earth's ancient oceans assisted and accelerated the interconversion of metabolites that in modern organisms make up glycolysis and the pentose-phosphate pathways, two of the essential and most centrally placed reaction cascades of metabolism," says Dr. Markus Ralser, Group Leader at the Department of Biochemistry at the University of Cambridge and the National Institute for Medical Research. "In our reconstructed version of the ancient Archean ocean, these metabolic reactions were particularly sensitive to the presence of ferrous iron that helped catalyze many of the chemical reactions that we observed." From the analysis of early oceanic sediments, geoscientists such as Alexandra V. Turchyn from the Department of Earth Sciences at the University of Cambridge, one of the co-authors of the study, concluded that soluble forms of iron were one of the most frequently found molecules in the prebiotic oceans. {…}Journal Reference: Markus A Keller, Alexandra V Turchyn, Markus Ralser. Non"enzymatic glycolysis and pentose phosphate pathway"like reactions in a plausible Archean ocean. Molecular Systems Biology, 2014; DOI: 10.1002/msb.20145228